Material Safety Data for AVERSION® (Denatonium Benzoate)

  1. SUPPLIER INFORMATION
  2. PRODUCT INFORMATION
  3. HAZARDOUS INGREDIENTS
  4. PHYSICAL CHARACTERISTICS
  5. FLAMMABILITY  & REACTIVITY
  6. FLAMMABILITY  & REACTIVITY CONTINUED
  7. TOXICOLOGY
  8. PROTECTIVE EQUIPMENT
  9. ENVIRONMENT
  10. STORAGE  & HANDLING
  11. FIRST AID
 
1. SUPPLIER INFORMATION

C Tech Corporation.

5B, Himgiri, 1277 Hatiskar Marg,
prabhadevi, Mumbai-400025,
India.

Telephone: +(91) 22 24301058
Fax: +(91)22 2430-9295
E-mail: response@ctechcorporation.com
 
2. PRODUCT INFORMATION

Product Identification Number:
not regulated for transport

Shipping Name:
not regulated for transport

Transport of Dangerous Goods Class:
not regulated for transport

WHMIS Class:
D 2B

Material Use:
bitter flavouring, denaturant for alcohol, pest repellent

*U.S. regulations may assign UN numbers to non-regulated substances
 
3. HAZARDOUS INGREDIENTS

 
CAS NUMBER
%
  TWAEVppm = mg/m3
      LD50RAL
(mg/kg)
SKIN
LC50 ppm
INHALATION
Ammonium, benzyldiethyl ((2,6-zylylcarbamoyl) methyl)-, benzoate
3734-33-6
   100%
not listed
584(rat) 508(rabbit)
not known
not known
 
4. PHYSICAL CHARACTERISTICS

Odour & Appearance:
Odourless white powder/granules with extremely bitter taste (taste threshold 50 parts per billion - exceedingly bitter at 20 parts per million)

Odour Threshold: none - odourless

Vapour Pressure: not known

Evaporation Rate: not known - not volatile

Vapour Density (air = 1): not known

Boiling Point: not known

Melting Point: 166oC - 170oC

Specific Gravity: not known - heavier than water

Water Solubility: 45g/litre (20oC)

Solubility in other solvents: highly soluble in alcohols (100g/l - 700g/l), slightly soluble in ketones, esters

pH: 6.5-7.5 - 3% solution (neutral)
 
5. FLAMMABILITY  & REACTIVITY

Flash Point:
none – material not volatile

Autoignition Temperature: not known – low fire hazard, but airborne dust may ignite under certain conditions

Flammable Limits: not known

Hazardous Combustion Products: carbon monoxide, nitrogen oxides, acrid smoke, partly oxidised hydrocarbon fragments

Firefighting Precautions: as for materials sustaining fire - firefighters must wear SCBA

Material Safety Data for AVERSION® (Denatonium Benzoate)
 
6. FLAMMABILITY  & REACTIVITY CONTINUED

Sensitivity to Static Discharge:
not sensitive - not a static accumulator

Sensitivity to Mechanical Impact: not sensitive

Chemical Stability: stable; will not polymerize

Reactive With: strong oxidizing agents

Dangerous Decomposition Products: none apart from Hazardous Combustion Products
 
7. TOXICOLOGY

(a) EFFECTS OF ACUTE EXPOSURE


Skin Contact: commercial products containing this substance may irritate, causing redness no reported effect from people exposed to the pure substance

Skin Absorption: not known – there is no evidence for more than minor skin absorption of this product

Eye Contact: non-specific irritant (as inert dust)

Inhalation: commercial products containing this substance may cause asthma, however there has been no reported effect from people (workers) exposed to the pure substance

Ingestion: somnolence, tremor, ataxic gait reported from animal testing; no human symptoms reported from workplaces using this product

Note: : extreme bitterness of product makes ingestion highly unlikely!

(b) EFFECTS OF CHRONIC EXPOSURE

General: no information – no adverse effects reported

Sensitizing: no information – no adverse effects reported

Carcinogenic: not a known carcinogen or tumorigen

Reproductive Effect: no known effect in humans or animals

Synergistic With: not known

Estimated LD50: 508mg/kg (oral, rabbit), 584mg/kg (oral, rat), 850mg/kg (oral guinea pig)

Estimated LC50: not known
 
8. PROTECTIVE EQUIPMENT

Hands:
not required unless prolonged contact is likely - then use any impermeable substance

Eyes: safety glasses with side shields or chemical goggles

Respirator: local ventilation to control dust preferable to respirator; if not possible, dust/mist filter on a respirator

Clothing: no special garments recommended

NOTE: dust can penetrate clothing and be held in contact with skin for prolonged periods! Wash thoroughly after handling.

Material Safety Data for AVERSION ® (Denatonium Benzoate)
 
9. ENVIRONMENT

Leak Precaution:
dyke to control spillage and prevent environmental contamination

Fire Potential - a spark or extremely hot surface could ignite dust.

Dust control measures recommended.


Handling Spill: ventilate contaminated area; sweep carefully to collect, pick up using non-sparking aluminium or plastic shovels, and store in closed containers for disposal.

Waste Disposal: do not flush to sewer; may be incinerated in approved facility; dump in sanitary landfill if local regulations permit

Bioaccumulation: product is biodegradable and is not known to bioaccumulate.

Biodegradation: not known
 
10. STORAGE  & HANDLING

Store and use in a cool dry environment, away from sources of ignition, heat and oxidizing agents. Use with good ventilation or other means to control dust. Although this product is not considered flammable, if dust is generated, take care to avoid sparks - use non-sparking tools and explosion-proof electrical equipment nearby. Do not cut, drill, weld or grind on or near this container. Avoid prolonged contact with skin and wash work clothes frequently. An eye bath and safety shower should be available near the workplace. Although this product is moderately toxic by mouth, its extremely bitter taste makes accidental ingestion highly unlikely!

NOTE: Workplace dust control is important to minimize workers' exposure to this product. Workers should also wash hands and face with soap and water after handling this substance to ensure that the product's bitter taste does not appear in their food. If exposed to product dust, shower thoroughly after work.
 
11. FIRST AID

SKIN:
Wash with soap and plenty of water. Remove contaminated clothing and do not reuse until thoroughly cleaned or laundered.

EYES: Wash eyes with plenty of water, holding eyelids open. Seek medical assistance promptly if there is irritation.

INHALATION: Remove from contaminated area promptly. CAUTION: Rescuer must not endanger himself! If breathing stops, administer artificial respiration and seek medical aid promptly.

INGESTION: Unlikely route of exposure due to extremely bitter taste of product. Give plenty of water to dilute product. Do not induce vomiting (NOTE below). Keep victim quiet. If vomiting occurs, lower victim's head below hips to prevent inhalation of vomited material. Seek medical help promptly.

NOTE: Inadvertent inhalation of vomited material may seriously damage the lungs. The risk and danger of this is greater than the risk of poisoning through absorption of this product. The stomach should be emptied under medical supervision, after the installation of an airway to protect the lungs.
 
PLEASE ENSURE THAT THIS MSDS IS GIVEN TO AND EXPLAINED TO THE PERSON USING THIS PRODUCT.

Prepared for C Tech Corporation., by Chaitanya Joshi  Aug. 2000; revised May 2001

 
   
 
     © Copyright 2006 Ctech Corporation - All rights reserved